A family of [ni8] cages templated by μ6-peroxide from dioxygen activation
Perivolaris, Alexandros ; Stoumpos, Constantinos C. ; Karpinska, Jolanta ; Ryder, Alan G. ; Frost, Jamie M. ; Mason, Kevin ; Prescimone, Alessandro ; Slawin, Alexandra M. Z. ; Kessler, Vadim G. ; Mathieson, Jennifer S. ... show 3 more
Perivolaris, Alexandros
Stoumpos, Constantinos C.
Karpinska, Jolanta
Ryder, Alan G.
Frost, Jamie M.
Mason, Kevin
Prescimone, Alessandro
Slawin, Alexandra M. Z.
Kessler, Vadim G.
Mathieson, Jennifer S.
Repository DOI
Publication Date
2014-01-01
Type
Article
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Citation
Perivolaris, Alexandros; Stoumpos, Constantinos C. Karpinska, Jolanta; Ryder, Alan G.; Frost, Jamie M.; Mason, Kevin; Prescimone, Alessandro; Slawin, Alexandra M. Z.; Kessler, Vadim G.; Mathieson, Jennifer S.; Cronin, Leroy; Brechin, Euan K.; Papaefstathiou, Giannis S. (2014). A family of [ni8] cages templated by μ6-peroxide from dioxygen activation. Inorg. Chem. Front. 1 (6), 487-494
Abstract
A family of exceptionally thermally stable [Ni-8] cages is reported, each being templated by a rare eta(3):eta(3):mu(6)-O-2(2-) species produced by dioxygen activation, where the reducing agent for the O-2 reduction appears to be the ligand used in the reaction mixtures, which was found within the nickel cages in its oxidized form.
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Publisher
Royal Society of Chemistry (RSC)
Publisher DOI
10.1039/c4qi00048j
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Attribution-NonCommercial-NoDerivs 3.0 Ireland