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A family of [ni8] cages templated by μ6-peroxide from dioxygen activation

Perivolaris, Alexandros
; 
Stoumpos, Constantinos C.
; 
Karpinska, Jolanta
; 
Ryder, Alan G.
; 
Frost, Jamie M.
; 
Mason, Kevin
; 
Prescimone, Alessandro
; 
Slawin, Alexandra M. Z.
; 
Kessler, Vadim G.
; 
Mathieson, Jennifer S.
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Identifiers
http://hdl.handle.net/10379/13454
 https://doi.org/10.13025/24678
Publication Date
2014-01-01
Keywords
transition-metal-complexes, spectroscopic characterization, structural-characterization, peroxo intermediate, nickel(i) complex, crystal-structure, oxygen complexes, room-temperature, o-o, reactivity
Type
journal article
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Citation
Perivolaris, Alexandros; Stoumpos, Constantinos C. Karpinska, Jolanta; Ryder, Alan G.; Frost, Jamie M.; Mason, Kevin; Prescimone, Alessandro; Slawin, Alexandra M. Z.; Kessler, Vadim G.; Mathieson, Jennifer S.; Cronin, Leroy; Brechin, Euan K.; Papaefstathiou, Giannis S. (2014). A family of [ni8] cages templated by μ6-peroxide from dioxygen activation. Inorg. Chem. Front. 1 (6), 487-494
Abstract
A family of exceptionally thermally stable [Ni-8] cages is reported, each being templated by a rare eta(3):eta(3):mu(6)-O-2(2-) species produced by dioxygen activation, where the reducing agent for the O-2 reduction appears to be the ligand used in the reaction mixtures, which was found within the nickel cages in its oxidized form.
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Royal Society of Chemistry (RSC)
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