Publication

Photochemical co2reduction in water using a co-immobilised nickel catalyst and a visible light sensitiser

Neri, Gaia
; 
Forster, Mark
; 
Walsh, James J.
; 
Robertson, C. M.
; 
Whittles, T. J.
; 
Farràs, Pau
; 
Cowan, Alexander J.
Identifiers
http://hdl.handle.net/10379/13101
 https://doi.org/10.13025/26593
Publication Date
2016-01-01
Keywords
carbon-dioxide reduction, hybrid photocatalyst, molecular catalysts, cyclam cyclam, complex, photoreduction, 1,4,8,11-tetraazacyclotetradecane, system, electrodes, interfaces
Type
Article
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Citation
Neri, Gaia; Forster, Mark; Walsh, James J. Robertson, C. M.; Whittles, T. J.; Farràs, Pau; Cowan, Alexander J. (2016). Photochemical co2reduction in water using a co-immobilised nickel catalyst and a visible light sensitiser. Chem. Commun. 52 (99), 14200-14203
Abstract
A dye-sensitised CO2 reduction photocatalyst that operates in water is reported. Transient spectroscopy demonstrates that the facile co-immobilisation of a Ru dye and a Ni CO2 reduction electrocatalyst enables efficient on-particle electron transfer leading to photocatalytic activity that greatly exceeds the equivalent solution based system.
Funder
Publisher
Royal Society of Chemistry (RSC)
Publisher DOI
Rights
Attribution-NonCommercial-NoDerivs 3.0 Ireland
cbn
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Externally hosted open access publications with University of Galway authors (2)